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Argonne scientists have developed a simplified approach to removing metals and radionuclides from waste or process streams which could result in significant financial and environmental savings for a variety of industrial separations processes.
Financial savings come from reducing chemical purchases and capital expenditures, and environmental savings are brought about by allowing repeated re-use of process solutions, thus minimizing waste.
This new approach, which Argonne has patented, uses small magnetic particles with a chemical coating. The coating is a solvent containing an extractant that selectively attracts specific metals, said Argonne chemist and process developer Luis Nuñez (CMT).
These particles (from Cortex Biochem, Inc., San Leandro, Calif.) are poured into a tank containing a process or waste solution, where the coating extracts the low concentration of metal. The magnetic particles, and their metal baggage, are removed from the solution with magnets, Nuñez said.
The metal can be stripped from the particles, allowing both the metal and the particles to be recovered, while the process solution can be recycled to the plant. The extractants placed on the magnetic particles can be tailored to the need, for example, to remove radionuclides.
Compared to ion exchange processes, efficiencies with magnetic separation are as much as 100 times greater. The extractant coatings are effective in acidic and caustic conditions, eliminating problems and costs associated with neutralization. Unlike ion exchange and solvent extraction, this process is effective with fine particles.
This is an in-tank or near-tank process that is inherently simple, compact, low cost, and low maintenance. It could be applied in recovery, recycling, and waste minimization activities at many industrial sites. It would reduce the need for capital expenditure to address ever-increasing environmental compliance levels, greatly reduce the chemical inventory required for metals separation, and, in some applications, recover metals of potential commercial value. Among the industries in which this process could be applied are the electroplating, environmental, and mining/metallurgy industries.
The process has been demonstrated at bench scale for a wide variety of waste streams, and scaleup and pilot testing are planned. Scaleup has been successful in other applications of magnetic separation.

Energy conservation pays off again in 1997 as the laboraotory received its largest checksince becoming a member of the Commonwealth Energy Cooperative (CEEC). The check for $107,927 was presented to Argonne at an award ceremony at Navy Pier in Chicago.
Argonne became a member of the CEEC in 1992 and has since received approximately $500,000 from Com Ed for reducing electrical demand during peak periods. CEEC members, which include more than 200 companies, can be asked to reduce electrical demand during the months of June through September between noon and 8 p.m.
"All Argonne employees are to be congratulated for the energy savings achieved during the summer months of 1997," said CEEC Coordinator Jug Uppal (PFS).
At Argonne, employees are asked to turn off non-essential lights and equipment. Standby diesel generators are started to provide part of the necessary electrical supply. Argonne receives $35 from Com Ed for every kilowatt saved, making the diesel generators cost-effective.
This year, Argonne was asked to curtail power on three occasions, totaling 18 hours. Power consumption dropped by about 2,938 kilowatts. As a result, Argonne also receives a smaller electric bill.
"PFS organized a small group to plan for the demand periods which paid off dramatically," said Uppal. "The PFS maintenance group, managed by Rich Pagel, put forth an extra effort to run the diesel generators to optimize energy use, resulting in the cost savings."

Three new members have been named to the University of Chicago Board of Governors for Argonne National Laboratory: Pennsylvania State University Chemistry Professor Stephen J. Benkovic; Robert C. Dynes, chancellor of the University of California at San Diego; and Helen Petrauskas, vice president of environmental and safety engineering at Ford Motor Co.
The board provides guidance, oversight, direction and advice to laboratory management. Its 21 members are drawn from University of Chicago trustees, officials and faculty, representatives from other universities and industry leaders.
* Benkovic is Evan Pugh professor and Eberly Chair in chemistry at Pennsylvania State University. He has received many awards for his research on enzymes, catalysis and DNA replication, including the Alfred Bader Award of the American Chemical Society, and election to the American Academy of Arts and Sciences, the National Academy of Sciences and the Institute of Medicine.
He is a member of the American Chemical Society, the Federation of American Biologists, Sigma Xi and the Chemical Society.
* Dynes, a professor of physics, has held several posts at the University of California, San Diego, including senior vice chancellor for academic affairs and physics department chair. Previously, he worked for 22 years at AT&T Bell Laboratories, serving for seven years as director of chemical physics research. He has written 185 journal articles.
His research interests include the properties of ultra-thin films of conductors and superconductors (materials that conduct electricity with no resistance), and high-temperature superconductors.
Dynes is a member of the National Academy of Sciences, a fellow of the American Physical Society, the Canadian Institute of Advanced Research and the American Academy of Arts and Sciences. He received a Fritz London Award in Low Temperature Physics in 1994.
* Petrauskas coordinates Ford's safety, fuel economy and environmental protection planning, and is Ford's principal spokesperson on environmental and vehicle safety activities.
Petrauskas has served on a number of policy development organizations, including membership on the U.S. Alternative Fuels Council and the U.S. Board of Trustees of the Regional Development Center for Central and Eastern Europe. Petrauskas is a member of the Board of Directors of the Sherwin Williams Co. and MCN Energy.

Experimental Facilities Division Director Gopal Shenoy has been named a fellow of the American Physical Society.
The American Physical Society is an organization of more than 41,000 physicists worldwide. Election to fellowship represents peer recognition of outstanding contributions to physics through original research and publication and innovative application of physics to science and technology. The honor is limited to no more than one-half of one percent of the membership of the society.
Shenoy's citation honors him "for his contributions to the study of magnetic superconductors and his pioneering role and leadership in the development of the Advanced Photon Source."
The Advanced Photon Source is the nation's most powerful source of X-rays for pioneering experiments crucial for maintaining the nation's technological competitiveness. Research at the APS is expected to lead to new and improved electronics, chemicals, industrial materials, pharmaceutical goods, medical diagnostics and consumer products. The $467 million light source, two-thirds of a mile in circumference, is located on an 80-acre site at Argonne.
Shenoy's other honors include promotion to senior scientist in 1982, and the University of Chicago's Distinguished Performance Award, given in 1986 for developing the concept, design and plan for the APS.

The Argonne Chess Club will hold lunchtime speed-chess tournaments open to all employees Monday Feb. 16 and 23, and March 2 and 9 in Argonne-East's Building 362, room E188.
Entry fee is $1. All entry fees will be returned as prizes. The chess club will provide all needed equipment.
Games will be timed at 5 minutes each. The tournaments will use Swiss system pairings if more than six players enter, otherwise pairings will be round robin.
Registration ends at noon. Games will start at 12:05 p.m.
For more information, call Dave Baurac (OPA) at ext. 2-5584 or Bob Hill at ext. 2-4865.

An all-day forum designed to increase awareness of the applications and capabilities of the World Wide Web at the laboratory is planned for Tuesday, Feb. 10, in Argonne-East's Building 203 Auditorium.
Sponsored by the Electronics and Computing Technologies Division, the forum will begin at 9 a.m.
The event is intended for Argonne employees interested in learning how Argonne organizations have used the web to develop various applications to get work done.
Click here for a preliminary agenda of topics.

Art collectors, take note: the Human Resources Diversity Program Office is giving away 1997 commemorative holiday posters. Available posters include Black History Month, Asian American Month, Hispanic Heritage Month, Disability Month and Native American Month.
For more information, call Colleen Girard (HR) at ext. 3021.

Human Resources will offer classes in "Dealing with Difficult People" and "Technical Communication" at Argonne-East during February.
* Dealing with Difficult People (HR221) will teach participants to recognize and respond to aggression, defiance, anger and other difficult behaviors, how to deal with disruptive behavior and conflict in groups and how to give constructive feedback. Class will be held Tuesday, Feb. 24, from 8:30 a.m. to 4:30 p.m. in Building 362, Room F108. Cost is $125.
* Technical Communication (HR220) is a hands-on course for technical professionals. Participants will acquire the background to analyze and adapt to readers' needs, recognize barriers to accurate communication, revise and prepare manuscripts for publication. The course will be held on eight consecutive Wednesday afternoons beginning Feb. 18 in Building 201, Room 190A. Cost is $350.
Full class information, and enrollment forms for all HR classes, is available on the Human Resources home page at http://www.anl.gov/HR/home.html under "Performance Development." For more information, call Betty Iwan (HR) at ext. 2-3410.


Service awards for December include:
35 Years
Anthony J. Gorski (ASD), Donald L. Reigle (SEC), Gordon L. Veerman (ESH-FD).
25 Years
Mary M. Berillo (PFS-PMO), Arthur J. Goldman (OPS).
20 Years
Jacqueline J. Griffith (IPD-MED), Daniel J. Koste (RPS-SUP), Marianne M. Mintz (ES), Donald E. Newsom (DIS), Marion M. Oldham (HR), Marie Sovereign (RPS-ESW), Robert G. Wagner (HEP).
10 Years
Daniel J. Ciarlette (ASD), Michael T. Lanagan (ET), Stephanie Malak (TD), Marianne Noy (ED), Laura A. Schmidt (EMO-WMO).
5 Years
Kayong Burdi (OCF-BSS), Mary S. Mihelich (DEP), Angela Monczynski (IPD-TIS), Susan M. Rogers (OCF-ACT), Linda J. Shoudis (XFD), Timothy A. Smith (XFD).


NEW ARRIVALS
A boy, Wesley, born Nov. 3 to Albert Sheng (ASD); a boy, Ryan Christopher, born Oct. 27 to first-time parents Christopher Johnson (CMT) and Lisa Utschig-Johnson (CMT); a boy, Alexander George, born Oct. 2 to first-time parents Brent and Yolantha Siegfried (CMT); a boy, Alexander Peter, born Oct. 29 to Angie and Ian Foster (MCS); a boy, Wyatt, born Oct. 8 to Mike and Stephanie Vogler (RPS); a boy, Christopher Brandon, born Nov. 6 to Vern (RPS) and Monica Peterson (ENG); a boy, Sebastian, born Oct. 1 to Scarlet and Humberto Garcia (TD); a girl, Tara Jo, born Oct. 20 to Corey and Donna Shaw (RPS). Proud grandparents: a granddaughter, Amber Kathleen Miller, born Oct. 30 for Ed and Kathy Weeks (ECT); a grandson, Robert Jeffery Wulf Jr., born Sept. 24 for Betty Wulf (ECT) and Aunt Julie Wulf (XFD); a grandson, Nathan Scott, born for first-time grandmother Diane Hawk (EMO); a granddaughter, Hanna, born Nov. 23 for Jack and Dolores Lagerquist (RPS).
ACHIEVEMENTS
Jim Cavallo (DIS) received the 1997 Environmental Professional of the Year award from the Chicago chapter of the Association of Energy Engineers. Sharon Lesinski (PFS) received a bachelor's degree with highest honors in Business Administration from Lewis University. Tracy Rogness (OTD-PRA) received a bachelor's degree with a triple major in Business Administration, Finance and Economics from Lewis University. Gary Bette' (RPS) received a master's degree. Zach Batte', son of Gary Batte' (RPS) signed with Virginia Military Institute to play basketball.
WEDDINGS/ENGAGEMENTS
Congratulations to Laurie Langosch (APS) and Gary Scheiblein on their Oct. 10 wedding. Congratulations to Jennifer Fedder (RPS) and Randy Turnage on their Nov. 20 wedding. Congratulation to Deborah Blunt (EAD) and Bassel Nabelssi on their engagement.
GET WELL WISHES
Wishes for a speedy recovery to Ken Thompson (ASD) who is recovering from eye surgery.
WELCOME
MSD welcomes Joel Mesot, Maria Luisa Medarde Barragan, Xidong Chen, Peter Baumann and Ute Ruett. TD-AW welcomes Karen Toews and Karen Gore.
CONDOLENCES
Condolences to Jerry Lowe (RA) on the death of his mother; to Julie and Randy Hudson (MSD) on the death of their infant daughter, Jessica Joyce; to Phyllis Kay (EAD) on the death of her father-in-law; Jim Frego (EMO) on the death of his mother; to Eliane Lessner (ASD) on the death of her mother-in-law; to Mike Janeczko (RPS) on the death of his father; to Tammie Taylor (ENG) on the death of her daughter; Monte Windmiller (RPS) on the death of his mother; and to friends and family of Ken Amar (RPS) who passed away Oct. 8.
FAREWELL
Good luck to Mark Masek (IPD-TIS), William Sheehan (IPD-TIS), Lynda Narug (ES), Pam Maholtra (ES), Sue Rura (ES), Chris Foster (MSD), Patrick Caraher (DIS), Robert Kero (DIS), Michele McCusker-Whiting (DIS) and Cheryl Drugan (IPD-TCS) who have all left the laboratory.
CONTRIBUTORS
Thanks to this issue's contributors: Judy Beumer (MSD), Barbara Burke (ECT), Loretta Cescato (CMT), Bonnie Gianpetro (EMO), Gloria Griparis (IPD-TCS), Barb Hall (ASD), Eileen Johnson (RA), Sheila Jungman (MSD), Karen Kroczek (PFS), Cathy Nelson (IPD-TIS), JoAnn Parnell (ES) and Eleanor Robson (EAD).


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