Frontiers2002

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A nuclear fuel cycle based on Argonne’s pyroprocessing technology offers substantial improvements in waste management, proliferation resistance and economic potential compared to conventional processing technologies used overseas.

Fuel recycling: The key step is "electrorefining," which removes uranium, plutonium and the other actinides (highly radioactive elements with long half-lives) from the spent fuel, while keeping them mixed together so the plutonium cannot be used directly in weapons. Spent fuel from reactors that use metallic uranium fuel can go straight to the electrorefiner. Spent fuel from commercial reactors, which consists of uranium oxide, would first undergo an "oxide reduction" step to convert it to metallic form. Next, the uranium and other actinides are sent to the cathode processor to remove residual salts and cadmium from electrorefining. The actinides are cast into fresh fuel, while the salts and cadmium are recycled back into the electrorefiner.

Nuclear waste: The waste consists of two forms. The stainless steel cladding that encased the spent fuel is combined with noble metal fission products in a metallic waste form. Salts and other fission products are combined with zeolites and converted into a ceramic waste. Both metal and ceramic waste forms are highly radioactive when they are created, but in less than 400 years, their radioactivity decays so they are less toxic than the natural ore the original fuel came from.

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