Nanostructured 3-D Architectures
Mechanics and Physics of Deformation and Fracture in Nanomaterials for Biomimetics, Batteries, and Lightweight Structural Materials
Creation of extremely strong yet ultra-light materials can be achieved by capitalizing on the hierarchical design of 3-dimensional nano-lattices. Such structural metamaterials exhibit superior thermomechanical properties at extremely low mass densities (lighter than aerogels), making these solid foams ideal for many scientific and technological applications. The dominant deformation mechanisms in such “meta-materials”, where individual constituent size (nanometers to microns) is comparable to the characteristic microstructural length scale of the constituent solid, are essentially unknown.
To harness the lucrative properties of 3-dimensional hierarchical structures, it is critical to assess mechanical properties at each relevant scale while capturing the overall structural complexity.We present the fabrication of 3-dimensional nano-lattices whose constituents vary in size from nanometers to tens of microns to millimeters. We discuss the mechanical properties of a range of nano-sized solids with different microstructures, subjected to mechanical deformation in a custom-made in-situ nanomechanical instrument. Attention is focused on the interplay between the internal critical microstructural length scale of materials and their external limitations in revealing the physical mechanisms governing the mechanical deformation, where competing material- and structure-induced size effects drive overall properties.
We focus on the deformation and failure in nano structures and discuss size effects in nanomaterials in the framework of mechanics and physics of defects. Specific discussion topics include: nano-mechanical experiments on nano structures extracted from particular phases and containing specific boundaries and interfaces, flaw sensitivity in fracture of nano structures, and the creation of hollow nano-lattices for applications in biomedical devices, ultra lightweight Li-ion batteries, and damagetolerant cellular solids.